Greater Porosity with Redox Reaction Speeds Up MOF Color Change
نویسندگان
چکیده
منابع مشابه
Pyrazine-imide complexes: reversible redox and MOF building blocks.
The synthesis of the symmetric pyrazine imide ligand, N-(2-pyrazylcarbonyl)-2-pyrazinecarboxamide, (Hdpzca) and five new first row transition metal complexes of it are reported: [M(II)(dpzca)(2)], M(II) = Fe, Cu, Zn; [Cu(II)(dpzca)(H(2)O)(2)]BF(4), [Cu(II)(dpzca)(H(2)O)(3)](2)SiF(6). The crystal structures of Hdpzca, [Co(II)(dpzca)(2)], [Cu(II)(dpzca)(2)], {[Co(III)(dpzca)(2)](BF(4))}(2)·5CH(3)...
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ژورنال
عنوان ژورنال: Chem
سال: 2016
ISSN: 2451-9294
DOI: 10.1016/j.chempr.2016.07.002